<?xml version="1.0" encoding="UTF-8" ?><MD_Metadata xmlns="http://www.isotc211.org/2005/gmd" xmlns:gco="http://www.isotc211.org/2005/gco" xmlns:gml="http://www.opengis.net/gml" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.isotc211.org/2005/gmd http://www.isotc211.org/2005/gmd/gmd.xsd"><fileIdentifier><gco:CharacterString>georefid:2009-080334</gco:CharacterString></fileIdentifier><contact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode 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sediments</gco:CharacterString></title><date><CI_Date><date><gco:Date>2008-01-01</gco:Date></date><dateType><CI_DateTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode_publication">publication</CI_DateTypeCode></dateType></CI_Date></date><identifier><MD_Identifier><code><gco:CharacterString>georefid:2009-080334</gco:CharacterString></code></MD_Identifier></identifier><identifier><MD_Identifier><code><gco:CharacterString>doi:10.1016/j.orggeochem.2008.01.019</gco:CharacterString></code></MD_Identifier></identifier><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Schouten, Stefan</gco:CharacterString></individualName><organisationName><gco:CharacterString>Royal Netherlands Institute for Sea Research, Department of Marine Organic Biogeochemistry, Texel, Netherlands</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Baas, Marianne</gco:CharacterString></individualName><organisationName><gco:CharacterString>Integrated Geochemical Interpretation, United Kingdom</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Hopmans, Ellen 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(editor), Farrimond, Paul (editor), Advances in organic geochemistry 2007; proceedings of the 23rd international meeting on Organic geochemistry</gco:CharacterString></name><issueIdentification><gco:CharacterString>39 (8)</gco:CharacterString></issueIdentification><page><gco:CharacterString>1033-1038</gco:CharacterString></page></CI_Series></series></CI_Citation></citation><abstract><gco:CharacterString>Recent studies have shown that glycerol dialkyl glycerol tetraether (GDGT) lipids, thought be unique for (hyper)thermophilic archaea, are also present in non-thermophilic archaea and environments. In this study, an unusual H-shaped isoprenoid GDGT, in which the two biphytanyl carbon skeletons are covalently bound by a carbon-carbon bond, was unambiguously identified in a number of sediments from marine and lacustrine environments. Its abundance varies from 0.2% to 6% of isoprenoid GDGTs. The H-shaped isoprenoid GDGT was originally identified in hyperthermophilic archaea and its presence in marine and lacustrine sediments suggests it is also synthesized by certain non-thermophilic relatives, possibly Euryarchaeota. 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