<?xml version="1.0" encoding="UTF-8" ?><MD_Metadata xmlns="http://www.isotc211.org/2005/gmd" xmlns:gco="http://www.isotc211.org/2005/gco" xmlns:gml="http://www.opengis.net/gml" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.isotc211.org/2005/gmd http://www.isotc211.org/2005/gmd/gmd.xsd"><fileIdentifier><gco:CharacterString>georefid:2005-072227</gco:CharacterString></fileIdentifier><parentIdentifier><gco:CharacterString>georefid:2005-072223</gco:CharacterString></parentIdentifier><contact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information">information</CI_OnLineFunctionCode></function></CI_OnlineResource></onlineResource></CI_Contact></contactInfo><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_pointOfContact">pointOfContact</CI_RoleCode></role></CI_ResponsibleParty></contact><dateStamp><gco:DateTime>2011-06-23T00:00:00Z</gco:DateTime></dateStamp><dataSetURI><gco:CharacterString>http://sedis.iodp.org/pub-catalogue/index.php?id=10.2973/odp.proc.sr.191.007.2004</gco:CharacterString></dataSetURI><identificationInfo><MD_DataIdentification><citation><CI_Citation><title><gco:CharacterString>Geochemical study of ODP Leg 191 Site 1179 sediments; direct observation of Mn and Ce oxidation states</gco:CharacterString></title><date><CI_Date><date><gco:Date>2003-01-01</gco:Date></date><dateType><CI_DateTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode_publication">publication</CI_DateTypeCode></dateType></CI_Date></date><identifier><MD_Identifier><code><gco:CharacterString>georefid:2005-072227</gco:CharacterString></code></MD_Identifier></identifier><identifier><MD_Identifier><code><gco:CharacterString>doi:10.2973/odp.proc.sr.191.007.2004</gco:CharacterString></code></MD_Identifier></identifier><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Fukukawa, M.</gco:CharacterString></individualName><organisationName><gco:CharacterString>Hiroshima University, Department of Earth and Planetary Systems Science, Higashi-Hiroshima, Japan</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Takahashi, Y.</gco:CharacterString></individualName><organisationName><gco:CharacterString>University of Tokyo, Japan</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Hayasaka, Yasutaka</gco:CharacterString></individualName><organisationName><gco:CharacterString>Japan Marine Science and Technology Center, Japan</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Sakai, Y.</gco:CharacterString></individualName><organisationName><gco:CharacterString>Florida State University, United States</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Shimizu, H.</gco:CharacterString></individualName><organisationName><gco:CharacterString>Dalhousie University, Canada</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><organisationName><gco:CharacterString>Texas A&amp;M University, Ocean Drilling Program, College Station, TX, United States</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_publisher">publisher</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><presentationForm><CI_PresentationFormCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode_documentDigital">documentDigital</CI_PresentationFormCode></presentationForm><series><CI_Series><name><gco:CharacterString>In: Sager, William W., Kanazawa, Toshihiko, Escutia, Carlota, Araki, Eiichiro, Arney, James E., Carlson, Richard L., Downey, Warna S., Einaudi, Florence, Haggas, Sarah L., Hayasaka, Yasutaka, Hirata, Kenji, Horner-Johnson, Benjamin C., Mandernack, Kevin W., McCarthy, Francine M. G., Moberly, Ralph, Mochizuki, Masashi, Pedersen, Rikke Ohlenschlaeger, Salimullah, Ali R. M., Shinohara, Masanao, Werner, Carl-Dietrich, Proceedings of the Ocean Drilling Program; scientific results; Northwest Pacific Seismic Observatory and hammer drill tests; covering Leg 191 of the cruises of the drilling vessel JOIDES Resolution; Yokohama, Japan, to Apra Harbor, Guam; Sites 1179-1182; 16 July-8 September 2000</gco:CharacterString></name><issueIdentification><gco:CharacterString>191</gco:CharacterString></issueIdentification></CI_Series></series></CI_Citation></citation><abstract><gco:CharacterString>Depth profiles of major element and rare earth element (REE) abundances in sediment samples (mainly siliceous ooze and clay) recovered from Holes 1179B and 1179C at Site 1179, Ocean Drilling Program Leg 191 (41.4 degrees N, 159.6 degrees E) were determined. The oxidation states of Mn and Ce were determined by X-ray absorption near-edge structure. Some geochemical indicators were tested, including the MnO/TiO (sub 2) ratios, a bivariate diagram of La/Ce vs. Al (sub 2) O (sub 3) /(Al (sub 2) O (sub 3) +Fe (sub 2) O (sub 3) ), and other discrimination diagrams. The oxidation state of Mn is reduced Mn(II) in the depth profile below 0.60 meters below seafloor (mbsf), which is consistent with relatively low and high abundances of Mn in the sediments and pore waters, respectively. It is possible that the diagenetic effect on the oxidation state and abundance of Mn makes it difficult for the MnO/TiO (sub 2) ratio to reflect the depositional environment. The normalized ratio of La and Ce does not change very much with depth, suggesting that the diagenetic effect does not affect the REE signature in the sediments. On the diagram of La/Ce vs. Al (sub 2) O (sub 3) /(Al (sub 2) O (sub 3) +Fe (sub 2) O (sub 3) ), the sediments studied here plot at the boundary of the pelagic and continental margin fields. This suggests that continental material has contributed to the sediment to some degree, even though Site 1179 is in a pelagic region of the northwestern Pacific Ocean, &gt;1600 km from Japan.</gco:CharacterString></abstract><status><MD_ProgressCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode_completed">completed</MD_ProgressCode></status><descriptiveKeywords><MD_Keywords><keyword><gco:CharacterString>Geochemistry of rocks, soils, and sediments</gco:CharacterString></keyword><keyword><gco:CharacterString>Oceanography</gco:CharacterString></keyword><keyword><gco:CharacterString>cerium</gco:CharacterString></keyword><keyword><gco:CharacterString>chemical composition</gco:CharacterString></keyword><keyword><gco:CharacterString>chemical ratios</gco:CharacterString></keyword><keyword><gco:CharacterString>geochemistry</gco:CharacterString></keyword><keyword><gco:CharacterString>Leg 191</gco:CharacterString></keyword><keyword><gco:CharacterString>major elements</gco:CharacterString></keyword><keyword><gco:CharacterString>manganese</gco:CharacterString></keyword><keyword><gco:CharacterString>marine sediments</gco:CharacterString></keyword><keyword><gco:CharacterString>metals</gco:CharacterString></keyword><keyword><gco:CharacterString>Mossbauer spectra</gco:CharacterString></keyword><keyword><gco:CharacterString>North Pacific</gco:CharacterString></keyword><keyword><gco:CharacterString>Northwest Pacific</gco:CharacterString></keyword><keyword><gco:CharacterString>Ocean Drilling Program</gco:CharacterString></keyword><keyword><gco:CharacterString>ocean floors</gco:CharacterString></keyword><keyword><gco:CharacterString>ODP Site 1179</gco:CharacterString></keyword><keyword><gco:CharacterString>oxidation</gco:CharacterString></keyword><keyword><gco:CharacterString>Pacific Ocean</gco:CharacterString></keyword><keyword><gco:CharacterString>rare earths</gco:CharacterString></keyword><keyword><gco:CharacterString>sediments</gco:CharacterString></keyword><keyword><gco:CharacterString>Shatsky Rise</gco:CharacterString></keyword><keyword><gco:CharacterString>spectra</gco:CharacterString></keyword><keyword><gco:CharacterString>West Pacific</gco:CharacterString></keyword></MD_Keywords></descriptiveKeywords><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:191</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_campaign">campaign</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:191:site:1179</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_study">study</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:191</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_campaign">campaign</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><language><gco:CharacterString>English</gco:CharacterString></language><topicCategory><MD_TopicCategoryCode>geoscientificInformation</MD_TopicCategoryCode></topicCategory><extent><EX_Extent><geographicElement><EX_GeographicBoundingBox><westBoundLongitude><gco:Decimal>159.5700</gco:Decimal></westBoundLongitude><eastBoundLongitude><gco:Decimal>159.5800</gco:Decimal></eastBoundLongitude><southBoundLatitude><gco:Decimal>41.0400</gco:Decimal></southBoundLatitude><northBoundLatitude><gco:Decimal>41.0500</gco:Decimal></northBoundLatitude></EX_GeographicBoundingBox></geographicElement></EX_Extent></extent><supplementalInformation><gco:CharacterString>Available only on CD-ROM in PDF format and on the Web in PDF or HTML</gco:CharacterString></supplementalInformation></MD_DataIdentification></identificationInfo><distributionInfo><MD_Distribution><distributionFormat><MD_Format><name><gco:CharacterString>application/pdf</gco:CharacterString></name><version><gco:CharacterString>unknown</gco:CharacterString></version><formatDistributor><MD_Distributor><distributorContact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information">information</CI_OnLineFunctionCode></function></CI_OnlineResource></onlineResource></CI_Contact></contactInfo><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_pointOfContact">pointOfContact</CI_RoleCode></role></CI_ResponsibleParty></distributorContact><distributorTransferOptions><MD_DigitalTransferOptions><onLine><CI_OnlineResource><linkage><URL>http://www-odp.tamu.edu/publications/191_SR/VOLUME/CHAPTERS/007.PDF</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_download">download</CI_OnLineFunctionCode></function></CI_OnlineResource></onLine></MD_DigitalTransferOptions></distributorTransferOptions></MD_Distributor></formatDistributor></MD_Format></distributionFormat></MD_Distribution></distributionInfo></MD_Metadata>