<?xml version="1.0" encoding="UTF-8" ?><MD_Metadata xmlns="http://www.isotc211.org/2005/gmd" xmlns:gco="http://www.isotc211.org/2005/gco" xmlns:gml="http://www.opengis.net/gml" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.isotc211.org/2005/gmd http://www.isotc211.org/2005/gmd/gmd.xsd"><fileIdentifier><gco:CharacterString>georefid:2003-038186</gco:CharacterString></fileIdentifier><contact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode 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Mya)</gco:CharacterString></title><date><CI_Date><date><gco:Date>2001-01-01</gco:Date></date><dateType><CI_DateTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode_publication">publication</CI_DateTypeCode></dateType></CI_Date></date><identifier><MD_Identifier><code><gco:CharacterString>georefid:2003-038186</gco:CharacterString></code></MD_Identifier></identifier><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Zachos, James C.</gco:CharacterString></individualName><organisationName><gco:CharacterString>University of California at Santa Cruz, Department of Earth Sciences, Santa Cruz, CA, United States</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" 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The Mi-1 event is characterized by an anomalous positive oxygen isotope excursion, the magnitude of which suggests the brief appearance of a full-scale ice-sheet on east Antarctica coupled with a few degrees of deep sea cooling. A recent breakthrough in extending the astronomical calibration back to approximately 30 Ma has provided a unique opportunity to compare the climatic events of the O/M transition relative to Earth's orbital variations. Here, we present an uninterrupted 5.5 My long high-fidelity chronology of late Oligocene-early Miocene climate and ocean carbon chemistry that is based on a composite isotope time series from two deep-sea cores (ODP Sites 926 and 929) collected in the western equatorial Atlantic. This unique isotope record provides a rare window into how the climate system responded to orbital forcing under boundary conditions significantly different from those of the recent past. Time-series analyses reveal climate variance concentrated at all Milankovitch frequencies, but with unusually strong power at the primary eccentricity band periods of 406, 125, and 95-ky. These cycles, which represent in part glacial advances and retreats of Antarctic ice-sheets, show significantly enhanced variability over a 1.6 My period (21.4-23.0 Ma) of suspected low greenhouse gas levels as inferred from the carbon isotope record. Perhaps the most unexpected finding is that of a rare orbital congruence between eccentricity and obliquity that precisely corresponds with the Mi-1 glaciation. This orbital anomaly involves approximately four consecutive cycles of low amplitude variance in obliquity (a node) during a period of low eccentricity. The net result is an extended period ( approximately 200 ky) of low seasonality orbits which allow for a step-like expansion of an Antarctic ice-sheet.</gco:CharacterString></abstract><status><MD_ProgressCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode_completed">completed</MD_ProgressCode></status><descriptiveKeywords><MD_Keywords><keyword><gco:CharacterString>Stratigraphy</gco:CharacterString></keyword><keyword><gco:CharacterString>ancient ice ages</gco:CharacterString></keyword><keyword><gco:CharacterString>Antarctica</gco:CharacterString></keyword><keyword><gco:CharacterString>Atlantic Ocean</gco:CharacterString></keyword><keyword><gco:CharacterString>boundary 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