<?xml version="1.0" encoding="UTF-8" ?><MD_Metadata xmlns="http://www.isotc211.org/2005/gmd" xmlns:gco="http://www.isotc211.org/2005/gco" xmlns:gml="http://www.opengis.net/gml" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.isotc211.org/2005/gmd http://www.isotc211.org/2005/gmd/gmd.xsd"><fileIdentifier><gco:CharacterString>georefid:2004-061127</gco:CharacterString></fileIdentifier><contact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information">information</CI_OnLineFunctionCode></function></CI_OnlineResource></onlineResource></CI_Contact></contactInfo><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_pointOfContact">pointOfContact</CI_RoleCode></role></CI_ResponsibleParty></contact><dateStamp><gco:DateTime>2011-06-23T00:00:00Z</gco:DateTime></dateStamp><dataSetURI><gco:CharacterString>http://sedis.iodp.org/pub-catalogue/index.php?id=2004-061127</gco:CharacterString></dataSetURI><identificationInfo><MD_DataIdentification><citation><CI_Citation><title><gco:CharacterString>Geochemical, sedimentological, and microbiotic responses to the late Miocene carbon isotope shift ( approximately 7.7 MA) at ODP Site 1172B in the south Tasman Sea</gco:CharacterString></title><date><CI_Date><date><gco:Date>2003-01-01</gco:Date></date><dateType><CI_DateTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode_publication">publication</CI_DateTypeCode></dateType></CI_Date></date><identifier><MD_Identifier><code><gco:CharacterString>georefid:2004-061127</gco:CharacterString></code></MD_Identifier></identifier><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Tedford, Rebecca Ann</gco:CharacterString></individualName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><presentationForm><CI_PresentationFormCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode_documentHardcopy">documentHardcopy</CI_PresentationFormCode></presentationForm><series><CI_Series><page><gco:CharacterString>63 pp.</gco:CharacterString></page></CI_Series></series></CI_Citation></citation><abstract><gco:CharacterString>A relatively complete Neogene section ( approximately 4.0-8.2 Ma) was recovered from the southern Tasman Sea (2,622 m), providing an excellent opportunity to investigate the responses of marine microplankton and carbonate chemistry to a permanent shift in the global dynamics of carbon cycling; an event referred to as the late Miocene carbon shift (LMCS). Parallel stable isotope records were generated through the study section using size-specific, depth-stratified planktonic (Globigerina bulloides, mixed-layer; Globoconella spp., thermocline) and benthic (Planulina wuellerstofi, Cibicidoides mundulus) foraminifera. All three delta (super 13) C curves record the LMCS, though the magnitude of this isotopic shift appears to decrease with increasing water depth. The onset of the LMCS predates the Tortonian/Messinian boundary, and coincides with magnetochron C4n.2n ( approximately 7.7 Ma). No significant increase is seen in the benthic delta (super 18) O record to indicate a substantial expansion of Antarctic ice sheets during the LMCS. The early stages of the LMCS are marked by a shoaling of the lysocline. This episode of intensified dissolution gave rise to a preservational bias among planktonic foraminiferal assemblages, most notably a decline in the relative abundance of G. bulloides that we attribute to species-selective dissolution. A curious aftereffect of the LMCS is that mixed-layer (G. bulloides) delta (super 13) C values converge upon benthic values, while thermocline (Globoconella spp.) values remain higher than benthic delta (super 13) C values. This delta (super 13) C inversion is due to a pronounced "vital effect" in the mixed-layer-dwelling G. bulloides that we attribute to either (1) increased uptake of metabolic (super 12) CO (sub 2) during calcification, or (2) increased [CO (sub 3) (super =) ] in seawater. The latter of these two explanations implies that oceanic pH increased following the LMCS, which may explain why post-LMCS carbonates take on a "modern" appearance with respect to their mean delta (super 13) C of Sigma CO (sub 2) .</gco:CharacterString></abstract><status><MD_ProgressCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode_completed">completed</MD_ProgressCode></status><descriptiveKeywords><MD_Keywords><keyword><gco:CharacterString>Stratigraphy</gco:CharacterString></keyword><keyword><gco:CharacterString>Isotope 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