<?xml version="1.0" encoding="UTF-8" ?><MD_Metadata xmlns="http://www.isotc211.org/2005/gmd" xmlns:gco="http://www.isotc211.org/2005/gco" xmlns:gml="http://www.opengis.net/gml" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.isotc211.org/2005/gmd http://www.isotc211.org/2005/gmd/gmd.xsd"><fileIdentifier><gco:CharacterString>georefid:2008-112977</gco:CharacterString></fileIdentifier><contact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information">information</CI_OnLineFunctionCode></function></CI_OnlineResource></onlineResource></CI_Contact></contactInfo><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_pointOfContact">pointOfContact</CI_RoleCode></role></CI_ResponsibleParty></contact><dateStamp><gco:DateTime>2011-06-23T00:00:00Z</gco:DateTime></dateStamp><dataSetURI><gco:CharacterString>http://sedis.iodp.org/pub-catalogue/index.php?id=2008-112977</gco:CharacterString></dataSetURI><identificationInfo><MD_DataIdentification><citation><CI_Citation><title><gco:CharacterString>Pelagic sediment, deep-water chemistry, and tectonics; an application of the history of biological sediment accumulation on the tectonic history of the Caribbean</gco:CharacterString></title><date><CI_Date><date><gco:Date>1990-01-01</gco:Date></date><dateType><CI_DateTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode_publication">publication</CI_DateTypeCode></dateType></CI_Date></date><identifier><MD_Identifier><code><gco:CharacterString>georefid:2008-112977</gco:CharacterString></code></MD_Identifier></identifier><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Donnelly, Thomas W.</gco:CharacterString></individualName><organisationName><gco:CharacterString>State University of New York, Department of Geological Sciences, Binghamton, NY, United States</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><organisationName><gco:CharacterString>Universita degli Studi di Milano, Istituto di Geologia, Dipartimento di Scienze della Terra, Milan, Italy</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_publisher">publisher</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><presentationForm><CI_PresentationFormCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode_documentHardcopy">documentHardcopy</CI_PresentationFormCode></presentationForm><series><CI_Series><name><gco:CharacterString>In: Gelati, R. (editor), Moratti, G. (editor), Neogene paleogeography of the western Mediterranean; problems related to the palinspastic reconstruction</gco:CharacterString></name><issueIdentification><gco:CharacterString>96 (2-3)</gco:CharacterString></issueIdentification><page><gco:CharacterString>143-164</gco:CharacterString></page></CI_Series></series></CI_Citation></citation><abstract><gco:CharacterString>The distribution of biogenic silica in pelagic sediment enables us to demonstrate that the Central American isthmus shoaled from 35 to 15 MA, gradually stopping the transfer of dissolved silica in intermediate ocean water into the Caribbean. Between 15 and 4.2 MA it continued to shoal, but during this interval the effective transfer of silica had ceased. A barrier existed at 40 MA between the west Atlantic and the Caribbean, probably on the site of the present Lesser Antilles - Aves Ridge. This barrier prevented the transfer of silica to the western Atlantic at the time of the removal of Atlantic intermediate and deep water silica by the newly formed North Atlantic Deep Water (NADW). The barrier was breached at about 19 MA, enabling silica from the Caribbean to penetrate at least to a few hundred km east of the Lesser Antilles (Site 543 DSDP). The Miocene-Pliocene boundary variation of the CCD recorded throughout the Atlantic is also seen at Site 29, within the Caribbean. This indicated that the breach formed at 19 MA was still open at this time. At a more recent time this breach has closed, probably by the collision of the southern Lesser Antilles and South America. The timing of the formation of barriers, which reflect the activity of subduction zones, as well as the horizontal extent of these barriers, can be established better using the biostratigraphic powers of pelagic sediment analysis than through conventional field geological investigations.</gco:CharacterString></abstract><status><MD_ProgressCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode_completed">completed</MD_ProgressCode></status><descriptiveKeywords><MD_Keywords><keyword><gco:CharacterString>Stratigraphy</gco:CharacterString></keyword><keyword><gco:CharacterString>Structural geology</gco:CharacterString></keyword><keyword><gco:CharacterString>Antilles</gco:CharacterString></keyword><keyword><gco:CharacterString>Atlantic Ocean</gco:CharacterString></keyword><keyword><gco:CharacterString>Aves 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