<?xml version="1.0" encoding="UTF-8" ?><MD_Metadata xmlns="http://www.isotc211.org/2005/gmd" xmlns:gco="http://www.isotc211.org/2005/gco" xmlns:gml="http://www.opengis.net/gml" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.isotc211.org/2005/gmd http://www.isotc211.org/2005/gmd/gmd.xsd"><fileIdentifier><gco:CharacterString>georefid:2011-035491</gco:CharacterString></fileIdentifier><contact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information">information</CI_OnLineFunctionCode></function></CI_OnlineResource></onlineResource></CI_Contact></contactInfo><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_pointOfContact">pointOfContact</CI_RoleCode></role></CI_ResponsibleParty></contact><dateStamp><gco:DateTime>2011-07-06T00:00:00Z</gco:DateTime></dateStamp><dataSetURI><gco:CharacterString>http://sedis.iodp.org/pub-catalogue/index.php?id=2011-035491</gco:CharacterString></dataSetURI><identificationInfo><MD_DataIdentification><citation><CI_Citation><title><gco:CharacterString>Increase in water column denitrification during the last deglaciation; the influence of oxygen demand in the eastern Equatorial Pacific</gco:CharacterString></title><date><CI_Date><date><gco:Date>2010-01-01</gco:Date></date><dateType><CI_DateTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode_publication">publication</CI_DateTypeCode></dateType></CI_Date></date><identifier><MD_Identifier><code><gco:CharacterString>georefid:2011-035491</gco:CharacterString></code></MD_Identifier></identifier><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Martinez, Philippe</gco:CharacterString></individualName><organisationName><gco:CharacterString>Universite de Bordeaux I, Environnements et Paleoenvironnements Oceaniques, Talence, France</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><individualName><gco:CharacterString>Robinson, Rebecca S.</gco:CharacterString></individualName><organisationName><gco:CharacterString>University of Rhode Island, United States</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_author">author</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><citedResponsibleParty><CI_ResponsibleParty><organisationName><gco:CharacterString>Copernicus GmbH on behalf of the European Union, Katlenburg-Lindau, International</gco:CharacterString></organisationName><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_publisher">publisher</CI_RoleCode></role></CI_ResponsibleParty></citedResponsibleParty><presentationForm><CI_PresentationFormCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_PresentationFormCode_documentDigital">documentDigital</CI_PresentationFormCode></presentationForm><series><CI_Series><name><gco:CharacterString>Biogeosciences</gco:CharacterString></name><issueIdentification><gco:CharacterString>7 (1)</gco:CharacterString></issueIdentification><page><gco:CharacterString>1-9</gco:CharacterString></page></CI_Series></series></CI_Citation></citation><abstract><gco:CharacterString>Here we present organic export production and nitrogen isotope results spanning the last 30 000 years from a core recovered off Costa Rica (Ocean Drilling Program (ODP) Site 1242) on the leading edge of the oxygen minimum zone of the Eastern Tropical North Pacific. Marine export production reveals glacial-interglacial variations with low organic matter (total organic carbon and total nitrogen) contents during warm intervals, twice more during cold episodes and double peaked maximum during the deglaciation, between approximately 15.5-18.5 and 11-13 ka B.P. When this new export production record is compared with four nearby cores from within the Eastern Pacific along the Equatorial divergence, good agreement between all the cores is observed. The major feature is a maximum of export during the early deglaciation. As for export production, water-column denitrification, represented by sedimentary delta (super 15) N records, along the Eastern tropical North and South Pacific between 15 degrees N and 36 degrees S is also coherent over the last deglaciation. Each of the nitrogen isotope profiles indicate that denitrification increased abruptly at 19 ka B.P to a maximum during the early deglaciation, confirming a typical Antarctic timing. It is proposed that the increase in export production and then in subsurface oxygen demand lead to an intensification of water-column denitrification within the oxygen minimum zones in the easternmost Pacific at the time of the last deglaciation. The triggering mechanism would have been primarily linked to an increase in preformed nutrients contents feeding the Equatorial Undercurrent driven by the resumption of overturning in the Southern Ocean and the return of nutrients from the deep ocean to the sea-surface. An increase in equatorial wind-driven upwelling of sub-surface nutrient-rich waters could have played the role of an amplifier.</gco:CharacterString></abstract><status><MD_ProgressCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ProgressCode_completed">completed</MD_ProgressCode></status><descriptiveKeywords><MD_Keywords><keyword><gco:CharacterString>Quaternary geology</gco:CharacterString></keyword><keyword><gco:CharacterString>biochemistry</gco:CharacterString></keyword><keyword><gco:CharacterString>carbon</gco:CharacterString></keyword><keyword><gco:CharacterString>Cenozoic</gco:CharacterString></keyword><keyword><gco:CharacterString>continental margin</gco:CharacterString></keyword><keyword><gco:CharacterString>deglaciation</gco:CharacterString></keyword><keyword><gco:CharacterString>denitrification</gco:CharacterString></keyword><keyword><gco:CharacterString>East Pacific</gco:CharacterString></keyword><keyword><gco:CharacterString>Equatorial Pacific</gco:CharacterString></keyword><keyword><gco:CharacterString>Holocene</gco:CharacterString></keyword><keyword><gco:CharacterString>late-glacial environment</gco:CharacterString></keyword><keyword><gco:CharacterString>Leg 202</gco:CharacterString></keyword><keyword><gco:CharacterString>marine environment</gco:CharacterString></keyword><keyword><gco:CharacterString>nitrates</gco:CharacterString></keyword><keyword><gco:CharacterString>nitrogen</gco:CharacterString></keyword><keyword><gco:CharacterString>North Pacific</gco:CharacterString></keyword><keyword><gco:CharacterString>Northeast Pacific</gco:CharacterString></keyword><keyword><gco:CharacterString>nutrients</gco:CharacterString></keyword><keyword><gco:CharacterString>ocean circulation</gco:CharacterString></keyword><keyword><gco:CharacterString>Ocean Drilling Program</gco:CharacterString></keyword><keyword><gco:CharacterString>ODP Site 1240</gco:CharacterString></keyword><keyword><gco:CharacterString>ODP Site 1242</gco:CharacterString></keyword><keyword><gco:CharacterString>organic carbon</gco:CharacterString></keyword><keyword><gco:CharacterString>oxygen</gco:CharacterString></keyword><keyword><gco:CharacterString>Pacific Ocean</gco:CharacterString></keyword><keyword><gco:CharacterString>paleo-oceanography</gco:CharacterString></keyword><keyword><gco:CharacterString>paleocurrents</gco:CharacterString></keyword><keyword><gco:CharacterString>Panama Basin</gco:CharacterString></keyword><keyword><gco:CharacterString>Quaternary</gco:CharacterString></keyword><keyword><gco:CharacterString>sea water</gco:CharacterString></keyword><keyword><gco:CharacterString>Southern Ocean</gco:CharacterString></keyword><keyword><gco:CharacterString>thermocline</gco:CharacterString></keyword><keyword><gco:CharacterString>thermohaline circulation</gco:CharacterString></keyword><keyword><gco:CharacterString>upwelling</gco:CharacterString></keyword><keyword><gco:CharacterString>winds</gco:CharacterString></keyword></MD_Keywords></descriptiveKeywords><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:202</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_campaign">campaign</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:202:site:1240</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_study">study</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:202</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_campaign">campaign</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:202:site:1242</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_study">study</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><aggregationInfo><MD_AggregateInformation><aggregateDataSetIdentifier><RS_Identifier><code><gco:CharacterString>urn:org.iodp:exp:202</gco:CharacterString></code><codeSpace><gco:CharacterString>urn</gco:CharacterString></codeSpace></RS_Identifier></aggregateDataSetIdentifier><associationType><DS_AssociationTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_AssociationTypeCode_largerWorkCitation">largerWorkCitation</DS_AssociationTypeCode></associationType><initiativeType><DS_InitiativeTypeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#DS_InitiativeTypeCode_campaign">campaign</DS_InitiativeTypeCode></initiativeType></MD_AggregateInformation></aggregationInfo><language><gco:CharacterString>English</gco:CharacterString></language><topicCategory><MD_TopicCategoryCode>geoscientificInformation</MD_TopicCategoryCode></topicCategory><extent><EX_Extent><geographicElement><EX_GeographicBoundingBox><westBoundLongitude><gco:Decimal>-83.3600</gco:Decimal></westBoundLongitude><eastBoundLongitude><gco:Decimal>-82.2800</gco:Decimal></eastBoundLongitude><southBoundLatitude><gco:Decimal>0.0100</gco:Decimal></southBoundLatitude><northBoundLatitude><gco:Decimal>7.5100</gco:Decimal></northBoundLatitude></EX_GeographicBoundingBox></geographicElement></EX_Extent></extent><supplementalInformation><gco:CharacterString>Published in Biogeosciences Discuss.: 19 May 2009, http://www.biogeosciences-discuss.net/6/5145/2009/bgd-6-5145-2009.html ; accessed in Feb., 2011; abstract: http://www.biogeosciences.net/7/1/2010/bg-7-1-2010.html</gco:CharacterString></supplementalInformation></MD_DataIdentification></identificationInfo><distributionInfo><MD_Distribution><distributionFormat><MD_Format><name><gco:CharacterString>application/pdf</gco:CharacterString></name><version><gco:CharacterString>unknown</gco:CharacterString></version><formatDistributor><MD_Distributor><distributorContact><CI_ResponsibleParty><organisationName><gco:CharacterString>SEDIS Publication Catalogue</gco:CharacterString></organisationName><contactInfo><CI_Contact><address><CI_Address><electronicMailAddress><gco:CharacterString>ana.macario@awi.de</gco:CharacterString></electronicMailAddress></CI_Address></address><onlineResource><CI_OnlineResource><linkage><URL>http://sedis.iodp.org/pub-catalogue/</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_information">information</CI_OnLineFunctionCode></function></CI_OnlineResource></onlineResource></CI_Contact></contactInfo><role><CI_RoleCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_RoleCode_pointOfContact">pointOfContact</CI_RoleCode></role></CI_ResponsibleParty></distributorContact><distributorTransferOptions><MD_DigitalTransferOptions><onLine><CI_OnlineResource><linkage><URL>http://www.biogeosciences.net/7/1/2010/bg-7-1-2010.pdf</URL></linkage><function><CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode_download">download</CI_OnLineFunctionCode></function></CI_OnlineResource></onLine></MD_DigitalTransferOptions></distributorTransferOptions></MD_Distributor></formatDistributor></MD_Format></distributionFormat></MD_Distribution></distributionInfo></MD_Metadata>